Simple Harmonic Oscillator
Consider the motion of a particle of mass
in the
simple harmonic oscillator potential
![$\displaystyle U(x)= \frac{1}{2}\,\kappa\,x^{\,2},$](img3257.png) |
(4.165) |
where
is the so-called force constant of the oscillator. According to classical physics, a particle
trapped in this potential executes simple harmonic motion at the angular frequency
. (See Section 1.3.6.)
The time-independent Schrödinger equation for a particle of mass
and energy
moving in a
simple harmonic potential becomes
![$\displaystyle \frac{d^{2}\psi}{dx^{2}} = \frac{2\,m}{\hbar^{2}}\left(\frac{1}{2}\,\kappa\,x^{2}-E\right)\psi.$](img3260.png) |
(4.166) |
[See Equation (4.71).] Let
![$\displaystyle y = \sqrt{\frac{m\,\omega}{\hbar}}\,x,$](img3261.png) |
(4.167) |
and
![$\displaystyle \epsilon = \frac{2\,E}{\hbar\,\omega}.$](img3262.png) |
(4.168) |
Equation (4.166) reduces to
![$\displaystyle \frac{d^{2}\psi}{dy^{2}} - (y^{2}-\epsilon)\,\psi = 0.$](img3263.png) |
(4.169) |
We need to find solutions to the previous equation that are bounded
at infinity; that is, solutions that satisfy the boundary
condition
as
.
Consider the behavior of the solution to Equation (4.169) in the limit
. As is easily seen, in this limit the equation simplifies somewhat to give
![$\displaystyle \frac{d^{2}\psi}{dy^{2}} - y^{2}\,\psi \simeq 0.$](img3266.png) |
(4.170) |
The approximate solutions to the previous equation are
![$\displaystyle \psi(y) \simeq A(y)\,{\rm e}^{\pm y^{2}/2},$](img3267.png) |
(4.171) |
where
is a relatively slowly varying function of
.
Clearly, if
is to remain bounded as
then we
must chose the exponentially decaying solution. This suggests that
we should write
![$\displaystyle \psi(y) = h(y)\,{\rm e}^{-y^{2}/2},$](img3270.png) |
(4.172) |
where we would expect
to be an algebraic, rather than an exponential, function of
.
Substituting Equation (4.172) into Equation (4.169), we obtain
![$\displaystyle \frac{d^{2}h}{dy^{2}} - 2\,y\,\frac{dh}{dy} + (\epsilon-1)\,h = 0.$](img3272.png) |
(4.173) |
Let us attempt a power-law solution of the form
![$\displaystyle h(y) = \sum_{i=0,\infty} c_i\,y^{\,i}.$](img3273.png) |
(4.174) |
Inserting this test solution into Equation (4.173), and equating the
coefficients of
, we obtain the recursion relation
![$\displaystyle c_{i+2} = \frac{(2\,i-\epsilon+1)}{(i+1)\,(i+2)}\,c_i.$](img3275.png) |
(4.175) |
Consider the behavior of
in the limit
.
The previous recursion relation simplifies to
![$\displaystyle c_{i+2} \simeq \frac{2}{i}\,c_i.$](img3276.png) |
(4.176) |
Hence, at large
, when the higher powers of
dominate, we
have
![$\displaystyle h(y) \sim C \sum_{j}\frac{y^{\,2 j}}{j!}\sim C\,{\rm e}^{\,y^{2}}.$](img3278.png) |
(4.177) |
It follows that
varies as
as
. This behavior is unacceptable,
because it does not satisfy the boundary condition
as
. The only way in which we can prevent
from blowing up as
is to demand that the power series (4.174) terminate at
some finite value of
. This implies, from the recursion relation
(4.175), that
![$\displaystyle \epsilon = 2\,n+1,$](img3281.png) |
(4.178) |
where
is a non-negative integer. Note that the number of terms in the power
series (4.174) is
. Finally, using Equation (4.168), we obtain
![$\displaystyle E = \left(\frac{1}{2}+n\right)\hbar\,\omega,$](img3283.png) |
(4.179) |
for
.
Hence, we conclude that a particle moving in a
harmonic potential has quantized energy levels that
are equally spaced. The
spacing between successive energy levels is
, where
is the classical oscillation frequency. Furthermore, the
lowest energy state (
) possesses the finite energy
. This is another example of zero-point energy. (See Section 4.3.1.)
It is easily demonstrated that the (normalized) wavefunction of the lowest
energy state takes the form
![$\displaystyle \psi_0(x) = \frac{{\rm e}^{-x^{2}/2\,d^{2}}}{\pi^{1/4}\!\sqrt{d}},$](img3286.png) |
(4.180) |
where
.