Fundamental Assumptions

The purpose of kinetic theory is to deduce the macroscopic properties of an ideal gas from the motions of its constituent molecules. The fundamental assumptions of kinetic theory are that a gas held in a container consists of a very large number of molecules that are in ceaseless motion. Moreover, these molecules are constantly colliding with one another, and also with the walls of container. Furthermore, the pressure acting on the walls of the container is the resultant of all of the reaction forces as the molecules strike and rebound from the walls.

We can make a number of simplifying assumptions in our exploration of kinetic theory. First, the volume of the molecules is assumed to be negligible. Second, the molecules are assumed not to exert forces on one another, except when they collide. Third, the collisions of the molecules with the walls are assumed to be specular. The first two assumptions merely ensure that we are dealing with an ideal gas.